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Huckel Aromaticity And Frost Circles Organic Chemistry Help  The Huckel aromaticity rules are Molecule is cyclic;In 1931, German chemist and physicist Erich Hückel proposed a theory to help determine if a planar ring molecule would have aromatic properties His rule states that if a cyclic, planar molecule has 4n2 π electrons, it is considered aromatic This rule would come to be known as Hückel's Rule 4n+2 rule explained